Molecular and isotopic characterization of organic samples from the wreck of the Saint-Etienne merchant ship (XVIIIth century): Identification of pitch,fat, hair and sulfur

The wreck U Pezzo, excavated within the Saint Florent Gulf in northern Corsica was identified as the pink, Saint Etienne, a merchant ship which sank on January 31, 1769. In order to determine the composition of organic materials used to coat the hull or to waterproof different parts of the pink, a study of several samples, using molecular biomarker and carbon isotopic analysis, was initiated. The results revealed that the remarkable yellow coat, covering the outside planks of the ship’s bottom under the water line, is composed of sulfur, tallow (of ox and not of cetacean origin) and black pitch which corresponds to a mixture called “couroi” or “stuff”. Onboard ropes had been submitted to a tarring treatment with pitch. Hairs mixed with pitch were identified in samples collected between the two layers of the hull or under the sheathing planking. The study also provides a key model for weathering of pitch, as different degrees of degradation were found between the surface and the heart of several samples. Accordingly, molecular parameters for alteration were proposed. Furthermore novel mixed esters between terpenic and diterpenic alcohols and the free major fatty acids (C_14:0, C_16:0, C_18:0) were detected in the yellow coat.     

Chemical and isotopic variations in the Wiśniówka Mała mine pit water,Holy Cross Mountains (south-central Poland)

In 2005 and 2006, hydrogeochemical study was carried out in the bipartite Wiśniówka Mała pit lake of the Holy Cross Mountains (south-central Poland). This is the largest acidic water body in Poland. This report presents the element concentrations in the water and sediment, stable sulfur and oxygen isotope ratios in the soluble sulfates, and stable oxygen isotope ratio in the water. The scope of the investigation also encompassed mineralogical examinations (scanning electron microscope, X-ray diffraction) of the sediment. The results of this study show that there is a spatial and temporal variability in concentrations of most elements and sulfur isotope ratios in the examined pit lake. The water of the western pond displayed a lower pH with a mean of 3.73 and higher conductivity (390 μS cm⁻¹) as well as higher concentrations of sulfates (156 mg L⁻¹) and most of the cations and anions. The concentrations of Fe²⁺ and Fe³⁺ averaged 0.8 and 0.4 mg·L⁻¹. In contrast, the eastern pond water revealed a higher pH (mean of 4.36), lower conductivity (293 μS cm⁻¹) and lower sulfate (90 mg L⁻¹) and trace metal levels. Similar variations were recorded in the stable sulfur isotope ratios. The δ³⁴S_V-CDT(SO₄ ²⁻) values in the water of the western pit pond were in the range of −6.7 to −4.6‰ (mean of −5.6‰), whereas that in the eastern pit pond ranged from −2.2 to −0.9‰ (−1.6‰). The alkalinity of the entire lake water was below 0.1 mg·L⁻¹ CaCO₃. No distinct difference in the δ¹⁸O_V-SMOW(SO₄ ²⁻) was noted between the western and eastern pit ponds. Compared to the Purple Pond in the Sudetes (Poland) and similar sites throughout the world, the examined pit lake is highlighted by distinctly low concentrations of sulfates, iron and other trace metals. Based on this and other studies performed in the Holy Cross Mountains, a conclusion can be drawn that the SO₄ ²⁻ in the Wiśniówka Mała pit lake water is a mixture of SO₄ ²⁻ derived from the following sources: (1) pyrite oxidation (especially in the western pond water), (2) leaching of soluble sulfates from soils and waste material, as well as (3) subordinate deposition of airborne sulfate precipitation.     

Applying numerical modeling for designing strategies of effective groundwater remediation

Selection of effective groundwater remediation scenarios is a complex issue that requires understanding of contaminants’ transport processes. The effectiveness of cleanup measures may be verified by fate and transport numerical modeling. The goal of this work was to present the usefulness of fate and transport modeling for planning, verification and fulfillment of effective groundwater remediation methods. Selection methodology was developed, which is based on results of numerical flow and transport modeling. A field site located in south-east Poland was selected as a case study, in which groundwater contamination of trichloroethene and tetrachloroethene was detected. The results indicated that “pump and treat” was the most effective among the studied remediation methods, followed by permeable reactive barrier and in situ chemical oxidation. Natural attenuation-based remediation was demonstrated to be the least suitable, as it requires the longest time to reach predefined remediation goals, principally due to low sorption capacity and unfavorable hydrogeochemical conditions for biodegradation. Fate and transport numerical modeling allowed simulating different remediation strategies, and thus the decision-making process was facilitated.     

Multi-sensor DInSAR applied to the spatiotemporal evolution analysis of ground surface deformation in Cerro Prieto basin,Baja California,Mexico, for the 1993–2014 period

The combined effects of active tectonics and anthropogenic activities, primarily geothermal resources exploitation for electricity production in Cerro Prieto geothermal field, influence the ground surface deformation in Cerro Prieto basin, Baja California, Mexico. In this study, a large set of multi-sensor C-band SAR images have been employed to reconstruct the spatiotemporal evolution of aseismic ground surface deformation that has affected Cerro Prieto basin from 1993 to 2014. Conventional DInSAR together with the interferograms stacking procedure was applied. The results showed that the study area presented considerable surface deformation (mainly subsidence) during the entire time of the investigation. The main changes in rate and pattern of surface deformation have a good correlation in time and space with the changes in production in the Cerro Prieto geothermal field. Comparison of LOS displacement maps from different viewing geometries, and decomposition (where possible) of LOS displacement into vertical and horizontal (east–west) components, revealed considerable horizontal displacement which mostly reflects the ground movement at and beyond the margin of the subsidence basin toward the areas of highest subsidence rates. In addition, the validation of the DInSAR results by comparing them against measurements from leveling surveys was performed, confirming the high reliably of satellite interferometry for the ground surface deformation rate mapping in the study area.     

Determination of volatile concentrations in fluorapatite of Martian shergottite NWA 2975 by combining synchrotron FTIR,Raman spectroscopy,EMPA, and TEM,and inferences on the volatile budget of the apatite host‐magma

We combined the focused ion beam sample preparation technique with polarized synchrotron‐based FTIR (Fourier transform infrared) spectroscopy, laser‐Raman spectroscopy, electron microprobe analysis (EMPA), and transmission electron microscope (TEM) analysis to identify and quantify structurally bound OH, F, Cl, and CO₃ groups in fluorapatite from the Northwest Africa 2975 (NWA 2975) shergottite. In this study, the first FTIR spectra of the OH‐stretching region from a Martian apatite are presented that show characteristic OH‐bands of a F‐rich, hydroxyl‐bearing apatite. Depending on the method of apatite‐formula calculation and whether charge balance is assumed or not, the FTIR‐based quantification of the incorporated OH, expressed as wt% H₂O, is in variably good agreement with the H₂O concentration calculated from electron microprobe data. EMP analyses yielded between 0.35 and 0.54 wt% H₂O, and IR data yielded an average H₂O content of 0.31 ± 0.03 wt%, consistent with the lower range determined from EMP analyses. The TEM observations implied that the volatiles budget of fluorapatite is magmatic. The water content and the relative volatile ratios calculated for the NWA 2975 magma are similar to those established for other enriched or intermediate shergottites. It is difficult to define the source of enrichment: either Martian wet mantle or crustal assimilation. Comparing the environment of parental magma generation for NWA 2975 with the terrestrial mantle in terms of water content, it displays a composition intermediate between enriched and depleted MORB.     

The circulation, water masses and sea-ice of Baffin Bay

The oceanographic, meteorological and sea-ice conditions in Baffin Bay are studied using historical hydrographic, satellite and meteorological data, and a set of current meter data from a mooring program of the Bedford Institute of Oceanography. Baffin Bay is partially covered by sea-ice all year except August and September. The interannual variation of the ice extent is shown to be correlated with winter air temperature. Available hydrographic data were used to study the water masses and the horizontal and vertical distribution of temperature/salinity. Three water masses can be identified – Arctic Water in the upper 100–300 m of all regions except the southeast, West Greenland Intermediate Water at 300–800 m in most of the interior of Baffin Bay, and Deep Baffin Bay Water in all regions below 1200 m. The temperature and salinity in Baffin Bay have limited seasonal variability except in the upper 300 m of eastern Davis Strait, northern Baffin Bay and the mouth of Lancaster Sound. Summer data have a temperature minimum at 100 m, which suggests winter convection does not penetrate deeper than this depth. Current meter data and results of a circulation model indicate that the mean circulation is cyclonic. The seasonal variation of the currents is complex. Overall, summer and fall tend to have stronger currents than winter and spring at all depths. Among the different regions, the largest seasonal variation occurs at the mouth of Lancaster Sound and the Baffin Island slope. Model generated velocity fields show a basic agreement with the observed currents, and indicate strong topographic control in the vicinity of Davis Strait and on the Greenland shelves. The model also produces a southward counter current on the Greenland slope, which may explain the observed high horizontal shears over the Greenland slope. Estimates of the volume and fresh water transports through Lancaster, Jones and Smith Sounds are reviewed. Transports through Davis Strait are computed from the current meter data. The balance of freshwater budget and sensitivity of the thermohaline circulation to freshwater transport are discussed.     

Background Concentrations of Nickel in the Sediments of the Carpathian Dam Reservoirs (Southern Poland)

The background nickel (Ni) concentrations in the sediments of two sub‐mountain reservoirs (Dobczyce and Czorsztyn) situated in the Carpathian Flysh (southern Poland) were evaluated. Ni concentrations (15.6–83.1 µg g^?1 dry wt.) in both reservoir sediments were affected mainly by the high background content of Ni in the surrounding watershed. Distribution of elevated Ni concentrations mostly revealed an impact of long‐range transport influenced by the flow of the main tributary. Ni spatial pattern was mainly influenced by mineral compounds of Fe, Mn, and Al, and to a lesser degree by organic matter content and silt and clay fractions of the sediments of both investigated reservoirs. Spatial distribution was additionally modified by hydrological conditions (flood events and course of the old river‐bed). In both reservoirs, substantial portions of Ni were bound to potentially immobile phases, i.e., moderately reducible and residual phases (64–82% in total). Laboratory experiments showed that changes in pH affected Ni leaching from the sediment to a small degree (at pH ～3 up to 19.9%). Our results indicated that Ni in these reservoirs has low mobility and, therefore, poses a low toxicological risk to aquatic organisms.     

The influence of atmospheric circulation on the type of precipitation (Krak��w, southern Poland)

The paper discusses the impact of atmospheric circulation on the occurrence of various types of precipitation. A 146-year-long precipitation record from Kraków spanning the period 1863?C2008 was used alongside a calendar prepared by Nied?wied? (1981, 2009) describing circulation types covering the period 1873?C2008 and air masses and atmospheric fronts covering the period 1951?C2008 in southern Poland. The influence of atmospheric circulation on precipitation was measured using the frequency, conditional probability and average daily totals of precipitation. Circulation types, air masses and atmospheric fronts exerted influences on precipitation as a result of the seasonal variations of the thermal and moisture properties of air masses. The impact is best expressed by circulation types as these combine the aspect of cyclonicity/anticyclonicity with that of the direction of air advection, the two elements which determine the physical properties of the air. On average, liquid precipitation prevailed in all circulation types, except the Ea type in which snowfall dominated over liquid precipitation. Depending on the season, one of the three types of circulation, Wa, Wc and Bc, were shown to coincide with the greatest amount of liquid and thunderstorm precipitation. There was no single dominant circulation type for mixed precipitation or snowfall. In summer, the circulation types Nc, NEc, Cc and Bc were the most favourable to liquid and thunderstorm precipitation in terms of both probability and totals. In winter, snowfall was the most favoured by the Ec type. Frontal precipitation was twice as likely to occur as air mass precipitation, with the exception of snowfall which was predominantly an air mass type of precipitation in terms of probability, but its greatest totals were recorded on atmospheric fronts.